Chloramination of nitrogenous contaminants (pharmaceuticals and pesticides): NDMA and halogenated DBPs formation

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Chloramination of nitrogenous contaminants (pharmaceuticals and pesticides): NDMA and halogenated DBPs formation.

Disinfection with chloramines is often used to reduce the production of regulated disinfection by-products (DBPs) such as trihalomethanes (THMs) and haloacetic acids (HAAs). However, chloramination can lead to the formation of N-nitrosamines, including N-nitrosodimethylamine (NDMA), a probable human carcinogen. Previous research used dimethylamine (DMA) as a model precursor of NDMA, but certain...

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Formation and speciation of nine haloacetamides, an emerging class of nitrogenous DBPs, during chlorination or chloramination.

Haloacetamides (HAcAms) are an emerging class of nitrogenous disinfection by-products (N-DBPs) of health concern. However, there are very limited data on the formation and speciation of the nine bromine- and chlorine-containing haloacetamides (HAcAm9). In the study, their formation and speciation during chlor(am)ination were investigated for a group of waters with a range of specific ultraviole...

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NDMA formation during chlorination and chloramination of aqueous diuron solutions.

Formation of the potent carcinogen N-nitrosodimethylamine (NDMA) during chlorine disinfection of water containing secondary amines is now generally acknowledged. The phenylurea herbicide diuron is one of the most widely used herbicides in California, has been frequently detected in California's water sources with a transient nature of appearance, and has a structure that suggests it might be an...

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Chloramination techniques to reduce NDMA formation during disinfection

Previous studies modeled NDMA formation during chlorine disinfection as arising from the oxidation of an unsymmetrical dimethylhydrazine intermediate formed from the reaction of monochloramine and dimethylamine. However, chlorination of wastewater effluents indicated that this mechanism could not account for a significant portion of the observed NDMA formation. Laboratory studies indicated that...

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Formation Mechanism of NDMA from Ranitidine, Trimethylamine, and Other Tertiary Amines during Chloramination: A Computational Study

Chloramination of drinking waters has been associated with N-nitrosodimethylamine (NDMA) formation as a disinfection byproduct. NDMA is classified as a probable carcinogen and thus its formation during chloramination has recently become the focus of considerable research interest. In this study, the formation mechanisms of NDMA from ranitidine and trimethylamine (TMA), as models of tertiary ami...

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ژورنال

عنوان ژورنال: Water Research

سال: 2011

ISSN: 0043-1354

DOI: 10.1016/j.watres.2011.03.035